The 59th ACM Awards was packed with memorable performances from duos, from Nate Smith and Avril Lavigne to Kelsea Ballerini and Noah Kahan to Chris Stapleton and Dua Lipa. But, when it comes to duets, it's hard to beat a performance by married couple Blake Shelton and Gwen Stefani.

Blake and Gwen went with a casual look for the red carpet. He wore jeans and a blazer with leather accents, and she wore a feather-inspired jacket with matching skirt and platform heelse.

us musicians gwen stefani l and blake shelton arrive for the 59th academy of country music awards acm at ford center in the star in frisco, texas, may 16, 2024 photo by suzanne cordeiro  afp photo by suzanne cordeiroafp via getty imagespinterest
SUZANNE CORDEIRO

The duo took the stage to perform "Purple Irises," a new song they released in February. Blake wore his classic jeans and jacket, while Gwen opted for an on-theme ensemble of head-to-toe purple sequins with an oversize flower and purple nails.

blake shelton gwen stefanipinterest
John Shearer

The two beamed at each other as they sang the romantic lyrics. Prime Video shared the clip on their Instagram account, and fans left comments like, "There needs to be a love story movie based on their love story," and "This whole performance made me smile so big! Love them ."

Others called out their performance as the standout of the night: "Best of the night!! Loved it and my gawwwd Gwen 😍" and "Best performance of the night! ❤️❤️❤️❤️🔥😍"

We agree, this was one of many incredible moments from the awards show. If you missed the ACM Awards, you can catch it in Prime Video or Freevee.

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Katie Bowlby
Digital Director

Katie Bowlby is Digital Director at Country Living, where she covers pop culture news including country music, Yellowstone, and all things HGTV, plus gift guides and product reviews. She has been with Country Living for more than 11 years. Before that, she worked for Southern Living. The Indiana University grad also stitches up the cross-stitch pattern for every issue of the magazine.